/ Home
/ SUBMISSION

/ The BJOC
/ Diamond Open Access
/ Journal Statistics
/ Editorial Board
/ Community
/ Call for papers

/ Latest Articles
/ Most accessed
/ Thematic issues
/ Volumes
/ Authors

/ Alerts

/ TWITTER
/ LINKEDIN
/ Mastodon
/ RSS FEED

Empty search

Article Type

Publication Date Range

Search Tips

This search combines search strings from the content search (i.e. "Full Text", "Author", "Title", "Abstract", or "Keywords") with "Article Type" and "Publication Date Range" using the AND operator.

Search Examples

aromatic	the word “aromatic”
aromatic aldehyde	the word “aromatic” OR “aldehyde”
+aromatic +aldehyde	both words “aromatic” AND “aldehyde”
+aromatic -aldehyde	the word “aromatic” but NOT “aldehyde”
“aromatic aldehyde”	the exact phrase “aromatic aldehyde”
benz*	words which begin with “benz”, such as “benzene” or “benzyl”
benz*yl	words that begin with “benz” and end with “yl”, such as “benzyl” or “benzoyl”
benzyl~	words that are close to the word “benzyl”, such as “benzoyl” (i.e., fuzzy search)

BROWSE
Latest Articles
Most accessed
thematic issues
volumes
authors

BROWSE

Latest Articles Most Accessed Thematic Issues Volumes Authors

Author

1 article(s) from Ruyet, Louise

Copper-based fluorinated reagents for the synthesis of CF₂R-containing molecules (R ≠ F)

Louise Ruyet and
Tatiana Besset

Beilstein J. Org. Chem. 2020, 16, 1051–1065, doi:10.3762/bjoc.16.92

PDF

Graphical Abstract

Scheme 1: Synthesis of the first isolable (NHC)CuCF₂H complexes from TMSCF₂H and their application for the sy...

Jump to Scheme 1

Scheme 2: Pioneer works for the in situ generation of CuCF₂H from TMSCF₂H and from n-Bu₃SnCF₂H. Phen = 1,10-p...

Jump to Scheme 2

Scheme 3: A Sandmeyer-type difluoromethylation reaction via the in situ generation of CuCF₂H from TMSCF₂H. ^a...

Jump to Scheme 3

Scheme 4: A one pot, two-step sequence for the difluoromethylthiolation of various classes of compounds via t...

Jump to Scheme 4

Scheme 5: A copper-mediated oxidative difluoromethylation of terminal alkynes via the in situ generation of a...

Jump to Scheme 5

Scheme 6: A copper-mediated oxidative difluoromethylation of heteroarenes.

Jump to Scheme 6

Scheme 7: Synthesis of difluoromethylphosphonate-containing molecules using the in situ-generated CuCF₂PO(OEt)...

Jump to Scheme 7

Scheme 8: Synthesis of difluoromethylphosphonate-containing molecules using in situ-generated CuCF₂PO(OEt)₂ s...

Jump to Scheme 8

Scheme 9: Synthesis of difluoromethylphosphonate-containing molecules using in situ-generated CuCF₂PO(OEt)₂ s...

Jump to Scheme 9

Scheme 10: Synthesis of (diethylphosphono)difluoromethylthiolated molecules using in situ-generated CuCF₂PO(OE...

Jump to Scheme 10

Scheme 11: Access to (diethylphosphono)difluoromethylthiolated molecules via the in situ generation of CuCF₂PO...

Jump to Scheme 11

Scheme 12: Synthesis of (phenylsulfonyl)difluoromethyl-containing molecules via the in situ generation of CuCF₂...

Jump to Scheme 12

Scheme 13: Copper-mediated 1,1-difluoroethylation of diaryliodonium salts by using the in situ-generated CuCF₂...

Jump to Scheme 13

Scheme 14: Pioneer works for the pentafluoroethylation and heptafluoropropylation using a copper-based reagent...

Jump to Scheme 14

Scheme 15: Pentafluoroethylation of (hetero)aryl bromides using the (Phen)CuCF₂CF₃ complex. ¹⁹F NMR yields wer...

Jump to Scheme 15

Scheme 16: Synthesis of pentafluoroethyl ketones using the (Ph₃P)Cu(phen)CF₂CF₃ reagent. ¹⁹F NMR yields were g...

Jump to Scheme 16

Scheme 17: Synthesis of (Phen)₂Cu(O₂CCF₂RF) and functionalization of (hetero)aryl iodides.

Jump to Scheme 17

Scheme 18: Pentafluoroethylation of arylboronic acids and (hetero)aryl bromides via the in situ-generated CuCF₂...

Jump to Scheme 18

Scheme 19: In situ generation of CuCF₂CF₃ species from a cyclic-protected hexafluoroacetone and KCu(Ot-Bu)₂. ¹⁹...

Jump to Scheme 19

Scheme 20: Pentafluoroethylation of bromo- and iodoalkenes. Only examples of isolated compounds were depicted.

Jump to Scheme 20

Scheme 21: Fluoroalkylation of aryl halides via a RCF₂CF₂Cu species.

Jump to Scheme 21

Scheme 22: Synthesis of perfluoroorganolithium copper species or perfluroalkylcopper derivatives from iodoperf...

Jump to Scheme 22

Scheme 23: Formation of the PhenCuCF₂CF₃ reagent by means of TFE and pentafluoroethylation of iodoarenes and a...

Jump to Scheme 23

Scheme 24: Generation of a CuCF₂CF₃ reagent from TMSCF₃ and applications.

Jump to Scheme 24

Album

Review

Published 18 May 2020

Full text

Other Beilstein-Institut Open Science Activities

/ Help / Support & Contact / Alerts / Privacy Policy / Terms & Conditions / Impressum

Copper-based fluorinated reagents for the synthesis of CF2R-containing molecules (R ≠ F)

Copper-based fluorinated reagents for the synthesis of CF₂R-containing molecules (R ≠ F)